| CAS Number | 1563-66-2 |
|---|---|
| Molecular Formula | C12H15NO3 |
| Molecular Weight | 221.256 g/mol |
| InChI Key | DUEPRVBVGDRKAG-UHFFFAOYSA-N |
| LogP | 2.32 |
| Synonyms |
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Applications:
Carbofuran Separation on Obelisc R HPLC Column
Carbofuran is one of the most acutely toxic insecticides used on field crops. It is banned in Europe, Canada, and as of 2009 was banned in the United States. The EURL included carbofuran as a target pesticide for the EUPT-CF9. Obelisc R was used to retain carbofuran and separate it from impurities. Obelisc R contains embedded ionic and hydrophobic groups which can assist in fine tuning separations. Method is LC/MS compatible and can be used as a general approach for analyzing carbofuran and other phenoxy acids.
| Column | Obelisc R, 4.6x150 mm, 5 µm, 100A |
| Mobile Phase | MeCN - 20% |
| Buffer | AmFm pH 3.0- 20 mM |
| Flow Rate | 1.0 ml/min |
| Detection | UV, 250 nm |
| Class of Compounds | Insecticide, Herbicide, Fungicide, Hydrophobic, Ionizable |
| Analyzing Compounds | Carbofuran |
Application Analytes:
Carbofuran
Carbofuran Separation on Primesep and Obelisc Mixed-Mode HPLC Columns
Carbofuran is one of the most acutely toxic insecticides used on field crops. It is banned in Europe, Canada, and as of 2009 was banned in the United States. The EURL (European Union Reference Laboratory), included carbofuran as a target pesticide for the EUPT-CF9 a proficiency test for cereals and feedingstuff that require muli-residue methods. Primesep B2 and Obelisc R were used to retain carbofuran and separate it from impurities. Primesep B2 contains embedded basic ion-pairing groups and Obelisc R contains embedded ionic and hydrophobic groups which can assist in fine tuning separations. Method is LC/MS compatible and can be used as a general approach for analyzing carbofuran and other phenoxy acids.
| Column | Primesep B2, 2.1x150 mm, 5 µm, 100A |
| Mobile Phase | Gradient MeCN - 10-70%, 15 min, 7 min hold |
| Buffer | Gradient AmAc pH 4,5- 20-50 mM, 15 min, 7 min hold |
| Flow Rate | 0.4 ml/min |
| Detection | UV, 250 nm |
| Column | Obelisc R, 2.1x150 mm, 5 µm, 100A |
| Mobile Phase | Gradient MeCN - 10-70%, 15 min, 7 min hold |
| Buffer | Gradient AmAc pH 4,5- 20-50 mM, 15 min, 7 min hold |
| Flow Rate | 0.4 ml/min |
| Detection | UV, 250 nm |
| Class of Compounds | Insecticide, Herbicide, Fungicide, Hydrophobic, Ionizable |
| Analyzing Compounds | Carbofuran |
Application Analytes:
Carbofuran
HPLC Separation of Carbofuran on Obelisc R and Primesep 100 Columns
Carbofuran is an insecticide notable for its high toxicity to vertebrates, especially birds; it is one of the most toxic to humans as well. While band in many countries such as the U.S. and Canada, it can be purchased over-the-counter in some countries such as Kenya. Carbofuran was considered a target pesticide by the EURL (European Union Reference Laboratory) for the EUPT-FF9 2015 a proficiency test for the analysis of a over a hundred pesticides. Obelisc R and Primesep 100 were used to analyze carbofuran. Primesep 100 separates by reverse-phase and utilizing embedded acidic ion-pairing groups. Obelisc R uses long hydrophobic chains and multiple ion-pairing groups.
| Column | Obelisc R, 2.1x150 mm, 5 µm, 100A |
| Mobile Phase | Gradient MeCN - 25-70%, 15 min |
| Buffer | Gradient AmAc pH 3.0- 30-60 mM, 15 min |
| Flow Rate | 0.4 ml/min |
| Detection | UV, 270 nm |
| Column | Obelisc R, 2.1x150 mm, 5 µm, 100A |
| Mobile Phase | Gradient MeCN - 10-70%, 15 min |
| Buffer | Gradient AmAc pH 3.0- 20-60 mM, 15 min |
| Flow Rate | 0.4 ml/min |
| Detection | UV, 270 nm |
| Column | Primesep 100, 2.1x150 mm, 5 µm, 100A |
| Mobile Phase | Gradient MeCN - 10-70%, 15 min |
| Buffer | Gradient AmAc pH 3.0- 20-60 mM, 15 min |
| Flow Rate | 0.4 ml/min |
| Detection | UV, 270 nm |
| Class of Compounds | Insecticide, Herbicide, Fungicide, Hydrophobic, Ionizable |
| Analyzing Compounds | Carbofuran |
Application Analytes:
Carbofuran