Folpet

CAS Number 133-07-3
Molecular Formula C9H4Cl3NO2S
Molecular Weight 296.550 g/mol
InChI Key HKIOYBQGHSTUDB-UHFFFAOYSA-N
LogP 2.85
Synonyms
  • Folpet
  • 2-[(Trichloromethyl)sulfanyl]-1H-isoindole-1,3(2H)-dione
  • 1H-Isoindole-1,3(2H)-dione, 2-[(trichloromethyl)thio]-
  • 133-07-3
  • Folpan) (N-(Trichloromethylthio)phthalimide
  • 5-21-11-00118
  • 1H-Isoindole-1,3(2H)-dione, 2-[(trichloromethyl)thio]-
  • 2-[(Trichloromethyl)thio]-1H-isoindole-1,3-(2H)-dione
  • 2-[(Trichloromethyl)thio]-1H-isoindole-1,3(2H)-dione
  • Acryptane
  • Cosan T
  • Fungitrol 11
  • Intercide TMP
  • N-(Trichlormethylthio)phthalimid
  • N-(Trichloromethylthio)phtalimide
  • N-(trichloromethylthio)phthalimide
  • N-(triclorometiltio)ftalimida
  • N-[(Trichloromethyl)thio]phthalimide
  • Orthofaltan 50
  • Orthophaltan
  • Phaltan
  • Phaltane
  • PHTHALIMIDE, N-[(TRICHLOROMETHYL)THIO]-
  • Phthaltan
  • Spolacid
  • Vinicoll
  • Acryptan
  • BRN 0193373
  • Caswell No. 464
  • Cosan I
  • EINECS 205-088-6
  • EPA Pesticide Chemical Code 081601
  • Fungitrol
  • Fungitrol II
  • Murphy's rose fungicide
  • Ortho phaltan 50W
  • Thiophal
  • N-(Trichlormethylthio)phthalimide
  • 2-((Trichloromethyl)thio)-1H-isoindole-1,3(2H)-dione
  • Troysan anti-mildew O
  • N-(Trichlor-methylthio)-phthalamid
  • Trichlormethylthioimid kyseliny ftalove
  • UNII-X5NFK36917
  • N-(trichloromethanesulfenyl)phthalimide
  • N-(trichloromethanesulphenyl)phthalimide
  • folpel
  • trichloromethylthiophthalimide
  • 1135442-81-7
  • 52306-33-9

Applications:


HPLC Separation of Folpet on Obelisc and Primesep Mixed-Mode Columns
 
Folpet is a nonsystemic fungicide which is used to prevent apple scab, cherry leaf spot, rose black spot, and rose mildew. A method for folpet was provided by the EURL-SRM, a proficiency test for sigle residue methods developed by the European Union Reference Laboratory. Folpet was retained and separated from impurities with Obelisc R and Primesep B2 columns. Primesep B2 contains embedded basic ion-pairing groups and Obelisc R contains embedded ionic and hydrophobic groups which can assist in fine tuning separations. Method can be used for dozens of other pesticides and is LC/MS compatible.
 

Condition 1

Column Primesep B2, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min,  7 min hold
Buffer Gradient AmAc pH 4,5- 20-50 mM, 15 min,  7 min hold
Flow Rate 0.4 ml/min
Detection UV, 250 nm
 

Condition 2

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min,  7 min hold
Buffer Gradient AmAc pH 4,5- 20-50 mM, 15 min,  7 min hold
Flow Rate 0.4 ml/min
Detection UV, 250 nm
   

Description

Class of Compounds  Insecticide, Herbicide, Fungicide,  Hydrophobic, Ionizable
Analyzing Compounds Folpet
 

Application Analytes:

Folpet

Folpet Analysis on Primesep 100 and Obelisc R HPLC Columns
  Folpet is a fungicide which is used to prevent a variety of fungal infections such as apple scab, cherry leaf spot, rose black spot, and rose mildew. Folpet was one of many pesticides studied by the EURL-SRM, a proficiency test for single residue methods developed by the European Union Reference Laboratory. Folpet was retained and separated from impurities with Obelisc R and Primesep 100 columns. Primesep 100 contains embedded acidic ion-pairing groups and Obelisc R contains embedded ionic and hydrophobic groups which can assist in fine tuning separations. Method can be used for dozens of other pesticides and is LC/MS compatible.

Condition 1

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 25-70%, 15 min
Buffer Gradient AmAc pH 3.0- 30-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Condition 2

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min
Buffer Gradient AmAc pH 3.0- 20-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Condition 3

Column Primesep 100, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min
Buffer Gradient AmAc pH 3.0- 20-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Description

Class of Compounds  Insecticide, Herbicide, Fungicide,  Hydrophobic, Ionizable
Analyzing Compounds Folpet
 

Application Analytes:

Folpet