Nabam

CAS Number 142-59-6
Molecular Formula C4H6N2Na2S4
Molecular Weight 256.330 g/mol
InChI Key UQJQVUOTMVCFHX-UHFFFAOYSA-L
LogP 1.12
Synonyms
  • Nabam-sodium
  • Disodium ethane-1,2-diyldicarbamodithioate
  • Carbamodithioic acid, N,N'-1,2-ethanediylbis-, sodium salt (1:2)
  • 142-59-6
  • Nabam (Ethylenebisdithiocarbamate, disodium) (Carbamodithioic acid, 1,2-ethanediylbis-, disodium)
  • Caswell No. 585
  • Chem BAM
  • Dithane A-40
  • Dithane D-14
  • EINECS 205-547-0
  • EPA Pesticide Chemical Code 014503
  • 1,2-Ethanediylbiscarbamodithioic acid disodium salt
  • Ethylenebis(dithiocarbamate), disodium salt
  • Ethylenebis(dithiocarbamic acid) disodium salt
  • Nabasan
  • Nafun IPO
  • NSC 147803
  • Parzate liquid
  • Sodium ethylenebis(dithiocarbamate)
  • Spring-bak
  • NSC 49511
  • Dinatrium-(N,N'-ethyleen-bis(dithiocarbamaat))
  • Ethylen-bis-dithiokarbaman sodny
  • N,N'-Etilen-bis(ditiocarbammato) di sodio
  • UNII-0L6N5662WT
  • Di-natrium-aethylenbisdithiocarbamat
  • Dinatrium-(N,N'-aethylen-bis(dithiocarbamat))
  • N,N'-ethylene bis(dithiocarbamate de sodium)
  • disodium N,N'-1,2-ethanediylbis(carbamodithioate)
  • disodium N,N'-ethane-1,2-diyldicarbamodithioate
  • disodium ethylene-1,2-bisdithiocarbamate
  • disodium ethylenebis(dithiocarbamate)
  • nabame
  • sodium ethylenebis(dithiocarbamate)
  • nabam

Applications:


Nabam Analysis on Mixed-Mode HPLC Columns
 
Nabam is a di-thiocarbamate fungicide which is used on soils and leaves to protect from a variety of diseases on fruits, vegitables, field crops, and turf. Obelisc R and Primesep B2 were used to retain nabam and separate it from impurities. Primesep B2 contains embedded basic ion-pairing groups while Obelisc R contains embedded ionic and hydrophobic groups which can assist in fine tuning separations. Method is LC/MS compatible and can be used as a general approach for analyzing nabam and dozens of other pesticides.
 

Condition 1

Column Primesep B2, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 25-70%, 15 min,  7 min hold
Buffer Gradient AmAc pH 3.0- 30-60 mM, 15 min,  7 min hold
Flow Rate 0.4 ml/min
Detection UV, 250 nm
 

Condition 2

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min,  7 min hold
Buffer Gradient AmAc pH 3.0- 20-60 mM, 15 min,  7 min hold
Flow Rate 0.4 ml/min
Detection UV, 250 nm
   

Description

Class of Compounds  Insecticide, Herbicide, Fungicide,  Hydrophobic, Ionizable
Analyzing Compounds Nabam
 

Application Analytes:

Nabam

HPLC Separation of Nabam on Mixed-Mode Columns
  Nabam is a pesticide that controls algae, bacteria and fungal growth in aquatic industrial settings, and food processing water systems such as those used for cane and beet sugar production. Analysis of nabam is useful outside of agricultural science and food production since it can be used as a biocide for industrial purposes. Primesep 100 and Obelisc R were used to analyze nabam. Method is LC/MS compatible, and can be used for dozens of pesticides.

Condition 1

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 25-70%, 15 min
Buffer Gradient AmAc pH 3.0- 30-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Condition 2

Column Obelisc R, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min
Buffer Gradient AmAc pH 3.0- 20-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Condition 3

Column Primesep 100, 2.1x150 mm, 5 µm, 100A
Mobile Phase Gradient MeCN - 10-70%, 15 min
Buffer Gradient AmAc pH 3.0- 20-60 mM, 15 min
Flow Rate 0.4 ml/min
Detection UV, 270 nm
 

Description

Class of Compounds  Insecticide, Herbicide, Fungicide,  Hydrophobic, Ionizable
Analyzing Compounds Nabam
 

Application Analytes:

Nabam